Chemical Route To Electronic Devices In Graphene

Chemical Route To Electronic Devices In Graphene - Electronics Featured Graphene
Schematic of the synthesis procedure for the nanoribbon heterostructures: Precursor molecules are converted through chemical synthesis into precisely controlled graphene nanoribbons. Credit: Aalto University, Utrecht University, TU Delft

Essential electronic components, such as diodes and tunnel barriers, can be incorporated in single graphene wires (nanoribbons) with atomic precision. The goal is to create graphene-based electronic devices with extremely fast operational speeds. The discovery was made in a collaboration between Aalto University and their colleagues at Utrecht University and TU Delft in the Netherlands. The work is published in Nature Communications.

The ‘wonder material’ graphene has many interesting characteristics, and researchers around the world are looking for new ways to utilise them. Graphene itself does not have the characteristics needed to switch electrical currents on and off and smart solutions must be found for this particular problem. “We can make graphene structures with atomic precision. By selecting certain precursor substances (molecules), we can code the of the electrical circuit with extreme accuracy,” explains Peter Liljeroth from Aalto University, who conceived the project together with Ingmar Swart from Utrecht University.

Seamless integration

The electronic properties of graphene can be controlled by synthesizing it into very narrow strips (graphene nanoribbons). Previous research has shown that the ribbon’s electronic characteristics are dependent on its atomic width. A ribbon that is five atoms wide behaves similarly to a metallic wire with extremely good conduction characteristics, but adding two atoms makes the ribbon a semiconductor. “We are now able to seamlessly integrate five atom-wide ribbons with seven atom-wide ribbons. That gives you a metal-semiconductor junction, which is a basic building block of electronic components,” according to Ingmar Swart.

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