Revealing a Hidden Spin Polarization in MoS2


Revealing a Hidden Spin Polarization in MoS2 - Other 2D materials research

Elia Razzoli/University of Fribourg

Photoemission spectroscopy has detected two different populations of spin-polarized electrons that are “hidden” within a layered, graphene-like material.

The layers inside certain materials can carry spin-polarized electrons, but this polarization is hidden to measurements that aren’t sufficiently localized. A new study using photoemission spectroscopy has detected the hidden spin polarization in a graphene-like material called molybdenum disulfide (MoS2). Unique to this work is the ability to target specific populations of spin-polarized electrons with circularly polarized light.

Polarized spins, which can be programmed to carry information, are traditionally produced with magnetic fields. However, researchers are actively exploring nonmagnetic methods that could prove faster and more versatile for processing spin information. So-called transition-metal dichalcogenides (TMDCs), which include MoS2, are nonmagnetic materials whose layers exhibit a crystal asymmetry that produces spin polarization. But the polarization is hidden because the polarization direction is opposite for adjacent layers, resulting in a net polarization of zero.

Previous work observed hidden spin polarization in a TMDC called tungsten diselenide by targeting the surface layer of the material (where the spin polarization points “up” out of the surface). Now, Elia Razzoli of the University of Fribourg, Switzerland, and his colleagues have demonstrated a way to probe the spin polarization of deeper layers. In their spin- and angle-resolved photoemission spectroscopy experiments with MoS2, circularly polarized photons with around 50 eV penetrated into the material, causing electrons to be ejected. The spins of these electrons depended on the polarization of the light. In agreement with this observation, the team’s calculations showed that left-handed (right-handed) light preferentially excites spin-up (spin-down) electrons in different layers of MoS2. The results suggest the possibility of devices in which polarized light selects and manipulates different spin populations within a bulk material.

This is published in Physical Review Letters.

Publication Journal: “Selective Probing of Hidden Spin-Polarized States in Inversion-Symmetric Bulk MoS2” ,E. Razzoli, T. Jaouen, M.-L. Mottas, B. Hildebrand, G. Monney, A. Pisoni, S. Muff, M. Fanciulli, N.?C. Plumb, V.?A. Rogalev, V.?N. Strocov, J. Mesot, M. Shi, J.?H. Dil, H. Beck, and P. Aebi, Phys. Rev. Lett. 118, 086402 – Published 22 February 2017